Also, atomic hydrogen dissolved in the steel lattice may embrittle areas of hard microstructures in carbon steel base metal or weldments. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stress corrosion cracking. H 2 s can cause sulfide stress cracking of stainless steels. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials when the environment contains wet h 2 s. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. Materials and corrosion trends in offshore and subsea oil and. Sscc is a specialized case of hydrogen cracking as it may be possible that sulfide stress corrosion cracking and hydrogen cracking proceed simultaneously. Absorbed hydrogen atoms could easily provoke different types of hydrogen damage followed by environmentallyassisted cracking, apart from hic, including also sulfide stress cracking ssc and.
Factors affecting the sulfide stress cracking performance. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Cracking mechanism an overview sciencedirect topics. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. As seen in figure 1, cracking was observed only on the tension side of ubend samples. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Sulfide stress cracking nace mr01752002, mr0175iso 15156. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Explains caustic embrittlement, season cracking, hydrogen embrittlement. The presence of flaws that concentrate stress or crevices that alter. Three different mechanisms involved in stress corrosion. Some researchers consider sulfidestress cracking a type of stresscorrosion cracking, while others consider it a type of hydrogen embrittlement. As a form of hydrogen stress cracking, ssc is a cracking mechanism in pipelines, facilities piping and any equipment that comes in contact with sour wet h2s service conditions.
Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. Abstract sulfide stress corrosion cracking ssc behavior of line pipe steel was investigated using the ssc test method in nace standard tm017777, testing of metals for resistance to sulfide. However, available data remains scarce, in particular, few studies if any have published sufficient details for a full examination of the mechanisms at work. Sulfide stress corrosion cracking of line pipe corrosion. Most of the attributions of the role of hydrogen in ssc are based on similar cracking. Environmental cracking is a broad term that includes corrosion fatigue, hightemperature hydrogen attack, hydrogen blistering, hydrogen embrittlement, liquid metal embrittlement, season cracking, caustic embrittlement, stress corrosion cracking, stepwise cracking, sulfide corrosion cracking and sulfide stress cracking. Iron is oxidized to the ferrous form at the anode and hydrogen sulfide undergoes a two step dissociation at the cathode as shown below. Nov 11, 2018 this explains the stress corrosion and the conditions. Sulfide stress cracking, stress corrosion cracking, and other mechanisms of cracking caused by h2s. This standard presents metallic material requirements to provide resistance to sulfide stress cracking ssc andor stress corrosion cracking scc for petroleum production, drilling, gathering and flow line equipment, and field processing facilities to be used in hydrogen sulfide h2sbearing hydrocarbon service. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require. There is a wide range of damage mechanisms that can occur due to the effect of hydrogen charging in wet h2s environments.
Ssc is one of the many environmental cracking mechanisms resulting in pipeline steels exposed to aqueous sour. Kallol mondal,department of metallurgy and material science,iit kanpur. A method for field evaluation of heat treatment to identify. There is a general agreement that plastic strain affects the resistance to sulphide stress cracking, even possibly for low amounts of strain and without significant changes in hardness. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled gas containing hydrogen sulfide. Mechanisms that have been proposed to explain embrittlement include the formation. Sulfide stress cracking of nickelcontaining lowalloy. The low alloy steels of steam turbine rotors are susceptible to scc in the presence of hydroxides such as naoh. Modeling and experimental insights of sulfide stress cracking. Hydrogen sulfide hsub 2s has long been associated with the cause of corrosion damage and sulfide stress cracking ssc in high strength steels and high hardness weldments used in oil and gas production, petroleum refining, and petrochemicalchemical processing. Sulfide stress cracking ssc is just one of several forms of hydrogen. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking.
The variation of the name is due to the lack of agreement in the mechanism of failure. Hydrogen embrittlement is a function of the hydrogen absorption characteristics of the metal in the aggressive environment, which is the formation of molecular hydrogen from atomic hydrogen within the metal structure 160. Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. The responsibility for safe application of alloys is defined as follows.
Sulfide stress cracking an overview sciencedirect topics. Segregation induced cracking occurs when low melting point constituents such as phosphorous, zinc, copper and sulfur compounds in the admixture separate during the weld solidification process. One of the types of material damage that can occur as a result of hydrogen charging is sulfide stress cracking ssc of hard weldments and microstructures, which is. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. Sulfide stress cracking nace mr01752002, mr0175iso. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. More extensive use of the wet fluorescent magnetic particle technique in recent years as a refinery equipment inspection tool has highlighted the extent and magnitude of the. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled gas containing hydrogen sulfide and sulfur compounds. Rosen 15 types of pipeline cracks inspection solutions. Is sulfide stress cracking an anodic or a cathodic process. Standard material requirements materials resistant to. It should not be confused with the term stress corrosion cracking which is an anodic. Atomic hydrogen either combines to form h2 at the metal surface or diffuses into.
Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. For ssc to occur, a metal must be exposed to hydrogen sulfide and under operating conditions conducive to ssc. Sulfide stress cracking of highstrength steels in laboratory. Standard material requirements materials resistant to sulfide. Hydrogen sulfide is a corrosive compound that can lead to sulfide stress cracking and promote hydrogen embrittlement. One of these chemical reactions involves hydrogen sulfide in sulfide stress cracking ssc, a significant problem for the oil and gas industries. These three cracking mechanisms are known as sulfide stress cracking ssc, hydrogeninduced cracking hic, and stress oriented hydrogen induced cracking sohic. Sulfide stress cracking, amine cracking, polythionic acid, carbonate cracking, wet h2s cracking.
The scope of the journal includes the latest developments in areas of corrosion metallurgy, mechanisms, predictors, cracking sulfide stress, stress corrosion, hydrogeninduced, passivation, and co 2 corrosion. For this reason, along with toxicity risks of hydrogen sulfide gas, it is essential that water muds be kept entirely free of soluble sulfides and especially hydrogen sulfide at low ph. Under the assumption that these vessels were adequately heat treated, the vessels owners do not normally take into consideration the high residual stresses which create favorable conditions for sulfide stress cracking ssc and other stress corrosion cracking type damage mechanisms. Pdf sulfide stress corrosion cracking and hydrogen. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogenassisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. The h2s causes the hydrogen to enter the metal structure rather than bubble off from the surface. Clscc chloride stress corrosion cracking mechanism china.
Sulfide stress cracking wikipedia republished wiki 2. Ssc is one of the many environmental cracking mechanisms resulting in pipeline steels exposed to aqueous sour service environments. Corrosionpedia what is sulfide stress cracking ssc. Sulfide stress cracking nace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. This type of cracking is referred to as stress oriented hydrogen induced cracking sohic. This phenomenon is a form of hydrogen embrittlement he that includes a crack initiation followed by a propagation step leading to failure. The first three cracking mechanisms are associated with the entry of atomic hydrogen into the carbon steel lattice. Sulfide stress cracking resistance of 95 and 110 ksi octg sour service grades under high partial pressure of h 2 s a contribution to corrosion mechanism understanding. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Abstract sulfide stress corrosion cracking ssc behavior of line pipe steel was investigated using the ssc test method in nace standard tm017777, testing of metals for resistance to sulfide stre. Polythionic acid stress corrosion cracking deterioration. Feb 10, 2014 environmental degradation of materials by dr.
Sulfide stress cracking of nickelcontaining lowalloy steels. Sulfide stress cracking oil and gas pipelines wiley. This is because insp 2 is linked to 581 sulfide stress cracking, which belongs to the same dme as 581amine cracking i. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Mechanisms of sulfide stress cracking from the above discussion, it would appear fortuitous that hydrogen is intimately connected with ssc failure.
Wet hydrogen sulfide cracking is a term used for a variety of stress corrosion cracking scc failure modes of carbon steel exposed to aqueous sour refinery environments. Effect of coldwork on sulphide stress cracking resistance. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible. Sulfide stress cracking sulfide stress cracking ssc occurs only on high strength hardness steels. The influence of chemical composition and microstructure of api linepipe steels on hydrogen induced cracking and sulfide stress corrosion cracking. Dunlop, thus, concluded that the eac mechanism was a form of scc, i. Other mechanisms of introduction of hydrogen into metal are galvanic corrosion, as well as chemical reactions with acids or other chemicals. Hydrogen embrittlement also known as hydrogen assisted cracking and hydrogeninduced cracking, describes the embrittling of metal after being exposed to hydrogen. One of the more common problems is ssc, sulfide stress cracking. Sulfide stress cracking ssc also known as sour gas cracking sour gas. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking.
This mechanism is referred as sulfide stress corrosion cracking sscc. Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low. Jul 25, 2017 it is now well known that ssc is a particular form of hydrogen stress cracking hsc in the presence of water and h 2 s. In parallel events, once atomic hydrogen is absorbed within the microstructure, it can also diffuse into solid solution, leading to local crystal embrittlement and ultimately stress corrosion cracking in the presence of residual or applied tensile stresses. Ansinace mr0175hd2003sg metals for sulfide stress cracking. Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. Sulfide stress corrosion cracking, also known as sulfide stress cracking ssc, is a stress corrosion cracking phenomena that occurs in the presence of hydrogen sulfide. High atomic hydrogen concentrations in carbon steel can lead to sulfide stress cracking ssc of these hard areas. Manufacturers and suppliers provide materials that meet. Sulfide stress cracking, modeling mechanism, octg martensitic pipes, kinetic of crack propagation, trapped and diffusible hydrogen overview quenched and tempered martensitic steels for oil country tubular goods can be subject to sulfide stress cracking when exposed to a sour environment.
Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Sulfide stress cracking ssc can occur when h2s is present in the reservoir and is in contact with highstrength steel commonly used in drilling, completing and production wells 1. Sulfide stress cracking mostly occurs in very highly acidic environments. Highstrength steels with improved sulfide stress cracking resistance. Dunlop named this type of eac sulfide corrosion stress cracking scsc, which is now an obsolete term.
Scc is most commonly seen on steam turbine disk blade root attachments. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Mechanisms of alternating current induced corrosion of carbon steel publication. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. These high strength steels may break due to sulfide stress cracking ssc if subjected to mechanical stress and an aggressive environment which depends on the h2s partial pressure and solution ph. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. Ssc is a form of spontaneous brittle breakdown in occurring in highstrength. It is a dangerous type of corrosion which produces some of the toughest technical.
The mechanism of sulfide stress cracking involves a combination of stress corrosion cracking and hydrogen embrittlement. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. Computer software ace apps for corrosion engineers has a module to determine when pwht or preheating is required. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation.
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